That's a dual angle layout
The first number (75°) is the Drilling Angle and measures the angle between a line (the reference line) drawn from the pin to the preferred spin axis (PSA/MB) of the ball and the line drawn from the pin through the PAP.
The Drilling Angle, affects the length of the skid phase of the ball. The smaller the number the sooner it rolls, the larger the number the later it rolls.
If the ball doesn't have a marked PSA/MB then typically the reference line is drawn from the pin through the CG.
The second number (3 3/4") is the Pin to P.A.P. measurement controls the amount of flare.
The third number (45°) is the VAL angle (Vertical Axis Line) and measures the angle between the line drawn (the reference line ) from the pin to the P.A.P. of the ball. The Vertical Axis Line (VAL) is a line perpendicular to the Grip Midline, through the Positive Axis Point.
It determines how fast the ball transitions through the phases of ball motion (Smaller the number the ball revs up faster and transitions quicker, larger the number the slower it does it).
Here's a chart with a example(now this layout will look slightly different on a ball, because a ball is sphere. But it shows the different parts)
click for 3D diagram
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